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Stereoselective Synthesis: Workbench Edition
- Houben-weyl, Methods of Organic Chemistry
Volume E21a-E21f ) 6 Volumes)
By J. Houben, Theodor Weyl
Description
- Publisher: Thieme Medical Publishers
Number Of Pages: 6990
[*]Publication Date: 1997-01
[*]Binding: Hardcover
English-language volumes) 6 )
Editors
G. Helmchen, Heidelberg, Germany
R. W. Hoffmann, Marburg, Germany
J. Mulzer, Frankfurt, Germany
E. Schaumann, Clausthal-Zellerfeld, Germany
The development of stereoselective methods of organic synthesis has been the major aim of research in organic chemistry for over a decade, both in academia and in industry. This central field of chemistry has now reached a stage of maturity such that a comprehensive, critical survey is called for. At last, Stereoselective Synthesis provides just that - a six-volume set of almost 7000 pages that evaluates the entire literature of stereoselective chemistry.
The principal part of the work is concerned with methods for stereoselective bond formation. Following the general introductory chapters covering principles, nomenclature, separation, and analysis, the chapters on individual synthetic methods are organized by the type of bond that is broken or formed. Common chiral auxiliaries, solvents, reagents, and catalysts are also covered comprehensively.
Volume E 21a
Part A. General Aspects
Nomenclature and Vocabulary of
Organic Stereochemistry,
Basic Principles of EPC Synthesis,
J. Mulzer
Determination of Enantiomeric
Purity
Direct Methods, V. Schurig
Formation of Diastereomers,
W. Lindner, G. Uray
Determination of Absolute and
Relative Configuration
. Nuclear Magnetic Resonance
Methods )Relative Configuration),
x ray
and Neutron Diffraction
Methods, G. Maas
. Chemical Methods, P. Welzel
Chiroptical Methods, J. Gawronski
Part B. Synthesis of Axially Chiral
Compounds
Allenes, C. J. Elsevier
Biaryls, G. Bringmann, R. Walter,
R. Weirich
Part C
Synthesis of Chiral Compounds by Bond
Disconnection, H.-J. Gais
Part D
Synthesis of Chiral Compounds by Bond
Formation
Formation of C—C Bonds
Alkylation Reactions
Chiral Nucleophiles, H. Ahlbrecht,
T. Norin, G. Fráter, H.-E. Högberg,
L.S. Liebeskind, J.S. McCallum,
P. Fey, W. Hartwig, G. Solladié
Chiral Electrophiles, D.S. Matteson,
P. Duhamel
Chiral Additives, J.M. Brown
Insertion into C—H Bonds, D.F. Taber
Volume E 21b
.( Addition to Carbonyl Groups (C=O)
Sigma-Type Organometallic Compounds,
R.M. Devant, H.-E. Radunz
Benzyl-Type Organometallic
Compounds, D. Hoppe
Allyl-Type Organometallic Compounds,
D. Hoppe, W.R. Roush,
Enolates, M. Braun, L.S. Liebeskind,
J.S. McCallum, W.-D. Fessner
Azaenolates or Nitronates, P. Fey,
W. Hartwig
Metalated Sulfoxides or Sulfoximides,
G. Solladié
Enzyme-Catalyzed Hydrocyanation,
F. Effenberger, T. Ziegler
( Addition to Imino Groups) (C=N)
Sigma-Type Organometallic Compounds,
N. Risch, M. Arend
Allylic and Allenic Organometallic
Compounds, N. Risch, M. Arend
Enolates and Related Compounds,
N. Risch, M. Arend
Strecker and Ugi Reactions, H. Kunz
N-Acyliminium Ion Additions,
W.N. Speckamp, H. de Koning
Reactions Involving Olefinic Double
Bonds
Vinylogous Substitution Reactions,
Y. Yamamoto
Addition to Alpha,Beta-Unsaturated
Carbonyl Compounds (Michael-Type
(Additions,
Y. Yamamoto, S.G. Pyne,
D. Schinzer, B.L. Feringa,
J.F.G.A. Jansen
Addition to Olefinic Double Bonds;
Enimines, Nitroalkenes, 4,5-Dihydrooxazoles,
Alpha,Beta-Unsaturated
Sulfones, Sulfoxides and
Sulfoximines, S.G. Pyne
Volume E 21c
. Addition of Free Radicals, B. Giese,
T. Göbel, B. Kopping, H. Zipse
. Addition of Carbenium Ions to
Olefinic Double Bonds and Allylic
Allylic Substitutions Catalyzed by
Transition
Complexes,
P. Metz, T. Lübbers
. Hydroboration of Olefinic Double
Bonds, M. Zaidlewicz
Addition to Olefinic Double Bonds
Catalyzed by Transition Metals,
Pericyclic Reactions
Cycloadditions, J. Jurczak, T. Bauer,
C. Chapuis, D. Craig, M. Cinquini,
F. Cozzi, W. , P. Binger, D. Fox,
B.B. Snider, J. Mattay, R. Conrads,
Ene Reaction, J.K. Whitesell
Volume E 21d
. Sigmatropic Rearrangements and
Electrocyclic Reactions, H. Frauenrath,
J. Kallmerten, J.M. Takacs,
.Formation of C—H Bonds
Protonation of Organometallic
Compounds, Enolates and
Nitronates, S. Hünig
Radical Reactions, B. Giese,
A. Ghosez, T. Göbel, H. Zipse
Reduction of Carbonyl Groups
(C=O)
. Hydrogenation, H. Brunner
Reduction with Metals, H.M.R. Hoffmann,
A.M. El Khawaga
Reduction with Metal Hydrides,
A.P. Davis, M.M. Midland, L.A. Morell
Hydrosilylation and Subsequent
Hydrolysis, A.P. Davis, H. Brunner
. Reduction with C—H Hydride
Donors, M.M. Midland, L.A. Morell,
-Catalyzed and Biomimetic
Reductions, M. Gottwald
.( Reduction of Imino Groups (C=N),
J. Martens
Reduction of Olefinic Double Bonds
Hydrogenation, U. Kazmaier,
J.M. Brown, A. Pfaltz, P.K. Matzinger,
Hydroboration and Hydroalumination,
M. Zaidlewicz
Sigmatropic Rearrangements,
D. Hasselmann
Formation of C—Hal Bonds,
R. Bohlmann
Volume E 21e
Formation of C—O Bonds
Oxygenation of Enolates, F.A. Davis,
B.-C. Chen
Hydroboration of Olefinic Double
Bonds Followed by Oxidation,
Hydrosilylation of Olefinic Double
Bonds Followed by Oxidation,
-Dihydroxylation of Olefinic Double
Bonds, C. Scolastico, G. Poli
. Epoxidation of Olefinic Double
Bonds, R. Schwesinger, J. Willaredt,
T. Bauer, A.C. Oehlschlager
Cyclization onto Olefinic Double
Bonds Forming Lactones and Ethers,
G. Cardillo, M. Orena, D. Savoia
Conjugate Addition of O-Nucleophiles,
A. Berkessel
Microbial Insertion of Oxygen into
C—H Bonds, K. Petzoldt
Allylic Oxidation with Singlet
Molecular Oxygen, A.G. Griesbeck,
. Allylic Oxidation with Selenium
Dioxide, W.-D. Woggon
. Sigmatropic Rearrangements,
K. Ritter
Formation of C—S Bonds, M. Mikolajczyk,
J. Drabowicz, P. Kielbasinski
Formation of C—Se or C—Te Bonds,
M. Mikolajczyk, J. Drabowicz,
.
Formation of C—N Bonds
Electrophilic Amination, G. Boche
. Addition to Olefinic Double Bonds,
G. Cardillo, M. Orena, D. Savoia
. Conjugate Addition of N-Nucleophiles,
K. Drauz, M. Schäfer,
. Allylic Substitution Catalyzed by
Palladium Complexes, P. Metz
Allylic Amination, J.K. Whitesell
. Sigmatropic Rearrangements,
K. Ritter
Formation of C—P Bonds,
M. Mikolajczyk, J. Drabowicz,
. Formation of C—Si Bonds,
M. Mikolajczyk, J. Drabowicz,
Formation of C—Sn Bonds,
M. Mikolajczyk, J. Drabowicz,
Volume E 21f
Appendix Survey of Chiral Auxiliaries,
Solvents, Reagents and Catalysts,
R. Herrmann
Author Index
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